One thing about the Duet: it does have an internal mixer that allows you to monitor directly from the inputs, giving you no latency. Read the Maestro manual or check the Apogee web site for a little tutorial on how to use it.
The bad thing is that if you are using any of logics internal effects for your track (either as an insert effect on your input, or as one one your track insert) you won't be able to hear them back without hearing both your input from Logic with it's latency as well as the Duet's direct input motor, that means your sound will be flanged or phased (technically not really, to do either the delay tome has to modulate), basically thin and strange.
So, you will need to turn down your record track when recording, and then turn it up when playing back. A bit of a pain, but you get NO latency at all.
I would really suggest you use an outboard mic pre/compressor combo, that way to can make your levels a bit more consistent with the compression. Otherwise your vocalists dynamics will make monitoring for both of you an issue: going from very soft to very loud for example.
I hope this isn't too confusing. I am assuming you have a bit of knowledge regarding signal paths and recording technique. If you don't, you might want to check out one of "Sound On Sound" magazines older tutorials own this. Any articles older than 6 months can be looked at, and frankly it is one of the very best resources of recording and technology out there in my opinion.
You can find SOS here:
http://www.soundonsound.com/
it is a great resource regardless of your experience. I have been in this industry for 28 years now, and do high end tech support for composers and writers here in La, and I still learn new things every month from SOS.
Good luck, and welcome to this new addiction ;-)
George